产品详情
- Molecular Formula:C7H13NO2
- Molecular Weight:143.186
- Vapor Pressure:0.0024mmHg at 25°C
- Refractive Index:1.464
- Boiling Point:267 °C at 760 mmHg
- PKA:2.48±0.40(Predicted)
- Flash Point:115.3 °C
- PSA：49.33000
- Density:1.062 g/cm3
- LogP:0.78790
(2R,4R)-4-Methylpiperidine-2-carboxylic acid(Cas 74892-81-2) Usage
InChI:InChI=1/C7H13NO2/c1-5-2-3-8-6(4-5)7(9)10/h5-6,8H,2-4H2,1H3,(H,9,10)/t5-,6-/m1/s1
74892-81-2 Relevant articles
A Concise, Enantiospecific Total Synthesis of Chilocorine C Fueled by a Reductive Cyclization/Mannich Reaction Cascade
Lisnyak, Vladislav G.,Snyder, Scott A.
, p. 12027 - 12033 (2020)
Among defensive alkaloids isolated from ...
Preparation method for argatroban intermediate
-
Paragraph 0063; 0064; 0065; 0067, (2018/11/03)
The invention discloses a preparation me...
Enantioselective synthesis of trans-4-methylpipecolic acid
Alegret, Carlos,Santacana, Ferran,Riera, Antoni
, p. 7688 - 7692 (2008/02/13)
(Chemical Equation Presented) An asymmet...
Asymmetric syntheses of enantiopure 4-substituted pipecolic acid derivatives
Agami, Claude,Bisaro, Fabrice,Comesse, Sebastien,Guesne, Sebastien,Kadouri-Puchot, Catherine,Morgentin, Remy
, p. 2385 - 2389 (2007/10/03)
(2R,4R)-4-Methylpipecolic acid and (2S,4...
74892-81-2 Process route
-
-
(2R,4S)-2-amino-6-methoxy-4-methyl-6-oxohexanoic acid
-
- 74892-81-2
(2R-trans)-4-Methyl-2-piperidinecarboxylic acid
Conditions
| Conditions | Yield |
|---|---|
|
With potassium borohydride; In water; at 1 - 60 ℃; for 3.5h;
|
83.1% |
-
-
C22H25NO2
-
- 74892-81-2
(2R-trans)-4-Methyl-2-piperidinecarboxylic acid
Conditions
| Conditions | Yield |
|---|---|
|
C22H25NO2; With hydrogen; [Rh(NBD)(PPh3)2]PF6; In ethanol; at 50 ℃; for 4h; under 760.051 Torr;
With palladium hydroxide, 20 wt% on carbon; hydrogen; In ethanol; water; at 23 ℃; for 5h; under 760.051 Torr;
|
86% |
74892-81-2 Upstream products
-
123811-73-4
4-Methyl-pyridine-2-carboxylic acid; hydrochloride
-
123811-83-6
(+/-)-cis-Boc-4-methylpipecolinic acid
-
1003-67-4
4-methylpyridine-1-oxide
-
1620-76-4
2-Cyano-4-methylpyridin
74892-81-2 Downstream products
-
123811-83-6
(+/-)-cis-Boc-4-methylpipecolinic acid
-
610786-78-2
(2R,4R)-1,4-dimethylpiperidine-2-carboxylic acid
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